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西安工业大学材料科学基础试题及答案分析 - 图文

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第一章 固体材料的结构 Chapter 1. The Structure of Materials

作业1:原版教材第105页第17题

17. Identify the plane in an FCC metal formed by the intercepts 1,-1,-2. What is the normal to this plane?

Solution:

1) the intercepts of this plane are 1,-1,-2; 2) The reciprocals of this plane are 1,-1,-reciprocals of the intercepts. 3) clear fractions, 4) site planes in parentheses (221) 5) The directions and planes which have same miller indices are perpendicular to each other.

作业2:原版教材第105页第18题

18. Calculate the angle between [100] and [111] in Al.

Solution:

The crystal structure of Al is Fcc. We can calculate the angle between [100] and [111] as

??z o y 1,taking the 2x cos??

uu'?vv'?ww'u?v?w?u'?v'?w'222222?1?1?0?1?0?11?0?0?1?1?1z 222222?13

??54.73?

o y x

作业3:原版教材第105页第19题

19. Construct a coordinate system at the center of a cubic unit cell with the axes parallel to the 100 directions. Determine the tetrahedral angle, the angle between directions from the origin to two ends of any face diagonal. Solution:

111??? OA:,,???111?

222??111??? OB:,,???111?

222??s? co?1?1?1?1?1?112?12?12?12?12?12?2??

33?3?2

作业4:原版教材第105页第21题

21. Give the indices of the points, directions, and planes in the cubic cells shown in Figure HP3.1.

Solution:

The first step is to select an origin and orient the coordinate axes. We have elected to use the bottom back left corner of the cube as our origin. z As shown in the figure; 1; 21Point B has coordinate 0,1,; 2Point A has coordinate 0,0,Plane F: The intercepts of F are 1,1, Take reciprocals: 1,1,2; Clear fraction: 1,1,2; Cite them into parentheses: ?112? Plane E: The intercepts of E: ?,?,1 Taking reciprocals: 0,0,1

Plane E 2 A B D 1; 2y Plane F x 1 C ???Direction C: 2号坐标 1,1,0 1号坐标:1,0,1 ?011?

??(1) Determine the coordinates of two points

(2) Subtract the coordinates of the second point from those of the first point; (3) Cleat fractions from the difference to give indices in lowest integer vales, 0,1,1

????(4) write the indices in square brackets without commas: ?011?

??????201??? (5) negative integer values are indicated by placing a bar over the integer. D: ?1) The coordinates of points G and H are 0,0,2) plane L:

(1) determine the intercepts of plane L:?11; 0,,0 respectively; 32111,, 223(2) take the reciprocals of the intercepts: -2,2,3 (3) clear fractions: -2,2,3 (4) cite planes in parentheses, placing bars over negative ???

indices: ?223?

??

???3) plane K: ?1,1,???110? ??Plane K J 114) directions: I 1点:?,1, 2点:0,1,0 22 2-1:

G I 11??,0,???101? 22???Plane L H J 2点:0,0,1 1点:-1,1,0 ??????? 1-2: -1,1,-1 ?111???111?

????作业5:原版教材第106页第22题

22. Give the indices of the points, directions, and planes in the cubic cells shown in Figure HP3.2.

Solution:

11???? Plane E: 1,?,? 1,-2,-2 ??122?

22??1??? Plane F: ?,?,1?0,?2,1??021?

2??A Plane E C B plane F D

1,0 211 Point B: ,?,?1

22 Point A: 0,? Direction B D:

D点坐标:0,0,-1

11??? D-B: ?,?,0??1,1,0??110?

22?? Direction C:(1) 1,-1,0 (2) 0,0,?1 21??? (1)-(2) 1,?1,?2,?2,1??221?

2??

Point H: 1,1,1

I 11Point G: ,,0

22Direction I: (1) 0,0,H Plane K 1 (2) 1,1,1 2Plane L G J 1????? (1)- (2) ?1,?1,???221? 2?? Direction J: (1) 1,1,0 (2) 0,1,0 (1)- (2) 1,0,0??100? Plane L: ?,11,?0,2,2??011? 22????Plane K: 1,1,1??111?

??

作业6:

Use a calculation to verify that the atomic packing factor for the FCC structure is 0.74. Solution:

In an FCC, there are four lattice points per cell: if there is one atom per lattice point, there are also four atoms per cell. The volume of one atom is 4πr3/3 and the volume of the unit cell is a3: Packing factor = 4×4πr3/3 a3

Since for FCC unit cell, a=4r/2, packing factor =o.74

作业7:

用金属键原理解释金属的以下几个特征:良好的导电导热性、正的电阻温度系数、不透明和良好的延展性。 解答:

1)导电导热性:

金属中的自由电子在外加电场作用下,能够沿着电场方向作定向运动,具有导电性。金属中正离子振动和自由电子的运动均可传递热量(能),表现出良好的导热性。 2)正的电阻温度系数:

温度升高时,金属正离子的振动加剧,与自由电子的碰撞几率加大,对自由电子的定向运动阻力增大,故具有电的电阻温度系数。 3) 不透明:

金属中自由电子能够吸收并随后辐射出投射到金属表面的光能。故金属不透明,且具有光泽。

4) 延展性:

金属键没有方向性和饱和性,对原子也没有选择性。当受外力原子发生相对移动时,金属正离子仍包围在电子气之中。金属键不会受到破坏。 作业8:

算出fcc、bcc晶体中四面体间隙和八面体间隙 大小,用原子半径rA表示,并注明原子间隙位置。 解答:

bcc:八面体间隙:最小rB?置(

a?rA?0.154rA,位2411rA,(面中心及各边中心) ,,1),a?223 四面体间隙:(

11,,1) 24?a??a?rB???????rA?0.25rA,

?2??4? fcc:八面体间隙:体心处(

22111,,),222rB?4arA ?rA?0.414rA,a?22 四面体间隙:体对角线

1313处:(,,),4444rB?3a?rA?0.25rA 4

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